![]() ![]() This critical supersaturation S c depends on the respective interfacial parameter ( ϕ 0 or h). Note that for both models B and C (for h < 0), there exists a critical supersaturation, where ideal wetting switches in (the nucleation barrier disappears). ![]() Figure 10(Color online) Nucleation barrier height ( W ) normalized by that from the classical spherical cap model ( W SC ) vs supersaturation ( S ) for models A (square), B (triangle), and C (diamond) at interface parameters ψ = 60 °, ϕ 0 = 0.673648, and h = − 0.083733, respectively, which all realize the same equilibrium contact angle. ![]()
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